Most of the fuel additive ethanol used in the U.S. is made from corn. But new research reveals that copper can turn carbon dioxide into ethanol without using corn or other plants.
Most cars and trucks in the United States run on a blend of 90 percent gasoline and 10 percent ethanol, a renewable fuel made primarily from fermented corn. But producing the 14 billion gallons of ethanol consumed annually by American drivers requires millions of acres of farmland.
A recent discovery by Stanford University scientists could lead to a new, more sustainable way to make ethanol without corn or other crops. This technology has three basic components: water, carbon dioxide and electricity delivered through a copper catalyst. The results are published in Proceedings of the National Academy of Sciences.
“One of our long-range goals is to produce renewable ethanol in a way that doesn’t impact the global food supply,” said study principal investigator Thomas Jaramillo, an associate professor of chemical engineering at Stanford and of photon science at the SLAC National Accelerator Laboratory.
“Copper is one of the few catalysts that can produce ethanol at room temperature,” he said. “You just feed it electricity, water and carbon dioxide, and it makes ethanol. The problem is that it also makes 15 other compounds simultaneously, including lower-value products like methane and carbon monoxide. Separating those products would be an expensive process and require a lot of energy.”
Scientists would like to design copper catalysts that selectively convert carbon dioxide into higher-value chemicals and fuels, like ethanol and propanol, with few or no byproducts. But first they need a clear understanding of how these catalysts actually work. That’s where the recent findings come in.
For the PNAS study, the Stanford team chose three samples of crystalline copper, known as copper (100), copper (111) and copper (751). Scientists use these numbers to describe the surface geometries of single crystals.
“Copper (100), (111) and (751) look virtually identical but have major differences in the way their atoms are arranged on the surface,” said Christopher Hahn, an associate staff scientist at SLAC and co-lead lead author of the study. “The essence of our work is to understand how these different facets of copper affect electrocatalytic performance.”
In previous studies, scientists had created single-crystal copper electrodes just 1-square millimeter in size. For this study, Hahn and his co-workers at SLAC developed a novel way to grow single crystal-like copper on top of large wafers of silicon and sapphire. This approach resulted in films of each form of copper with a 6-square centimeter surface, 600 times bigger than typical single crystals.
To compare electrocatalytic performance, the researchers placed the three large electrodes in water, exposed them to carbon dioxide gas and applied a potential to generate an electric current.
The results were clear. When the team applied a specific voltage, the electrodes made of copper (751) were far more selective to liquid products, such as ethanol and propanol, than those made of copper (100) or (111).
Ultimately, the Stanford team would like to develop a technology capable of selectively producing carbon-neutral fuels and chemicals at an industrial scale.
“The eye on the prize is to create better catalysts that have game-changing potential by taking carbon dioxide as a feedstock and converting it into much more valuable products using renewable electricity or sunlight directly,” Jaramillo said. “We plan to use this method on nickel and other metals to further understand the chemistry at the surface. We think this study is an important piece of the puzzle and will open up whole new avenues of research for the community.”
The Latest on: Sustainable source of ethanol
- ‘Carbon Farming’ Could Make US Agriculture Truly Greenon June 24, 2020 at 4:00 am
Today a Senate committee will hear about a bill that would help farmers adopt practices to release less carbon from the soil, reducing planetary warming.
- GP Global driving sustainable solutions across entire portfolioon June 17, 2020 at 4:16 am
GP Global has launched its first sustainability report, demonstrating its commitment to delivering sustainable outcomes across its entire portfolio for the preservation of the planet and its ...
- GP Global launches its first sustainability performance report, driving sustainable solutions across its entire portfolioon June 17, 2020 at 1:11 am
GP Global, a leading global diversified conglomerate today announced the launch of its first Sustainability Report, demonstrating its commitment to delivering sustainable outcomes across its entire ...
- 43. LanzaTechon June 16, 2020 at 3:25 am
LanzaTech uses microbes and waste gases to convert the resulting ethanol into chemicals and fuels, in turn producing low carbon products like jet fuel that make for a cleaner environment.
- LanzaJet Takes Off for Decarbonization of Aviation Sectoron June 14, 2020 at 9:29 pm
The funding will be used to build a demonstration plant that will produce 10 million gallons per year of SAF and renewable diesel starting from sustainable ethanol sources. Production is expected ...
- LanzaTech launches LanzaJeton June 3, 2020 at 3:50 pm
The funding will be used to build a demonstration plant that will produce 10 million gallons per year of SAF and renewable diesel starting from sustainable ethanol sources. Production is expected to ...
- LanzaJet launches to make renewable jet fuel a realityon June 3, 2020 at 2:21 pm
Over a 15-year stretch, LanzaTech has developed technologies that can turn carbon emissions into ethanol that can be used for chemicals and fuel. Today, the company announced the spin-out of LanzaJet, ...
- LanzaJet launches to make renewable jet fuel a realityon June 1, 2020 at 5:00 pm
The Chicago-based company has been developing processes to capture emissions from power plants and other sources and convert those emissions into ethanol by injecting them into microbe-filled vats.
via Google News and Bing News