Stanford researchers have developed an inexpensive device that uses light to split water into oxygen and clean-burning hydrogen.
The goal is to supplement solar cells with hydrogen-powered fuel cells that can generate electricity when the sun isn’t shining or demand is high.
Stanford University scientists have created a silicon-based water splitter that is both low-cost and corrosion-free. The novel device – a silicon semiconductor coated in an ultrathin layer of nickel – could help pave the way for large-scale production of clean hydrogen fuel from sunlight, according to the scientists. Their results are published in the Nov. 15 issue of the journal Science.
“Solar cells only work when the sun is shining,” said study co-author Hongjie Dai, a professor of chemistry at Stanford. “When there’s no sunlight, utilities often have to rely on electricity from conventional power plants that run on coal or natural gas.”
A greener solution, Dai explained, is to supplement the solar cells with hydrogen-powered fuel cells that generate electricity at night or when demand is especially high.
To produce clean hydrogen for fuel cells, scientists have turned to an emerging technology called water splitting. Two semiconducting electrodes are connected and placed in water. The electrodes absorb light and use the energy to split the water into its basic components, oxygen and hydrogen. The oxygen is released into the atmosphere, and the hydrogen is stored as fuel.
When energy is needed, the process is reversed. The stored hydrogen and atmospheric oxygen are combined in a fuel cell to generate electricity and pure water.
The entire process is sustainable and emits no greenhouse gases. But finding a cheap way to split water has been a major challenge. Today, researchers continue searching for inexpensive materials that can be used to build water splitters efficient enough to be of practical use.
“Silicon, which is widely used in solar cells, would be an ideal, low-cost material,” said Stanford graduate student Michael J. Kenney, co-lead author of the Science study. “But silicon degrades in contact with an electrolyte solution. In fact, a submerged electrode made of silicon corrodes as soon as the water-splitting reaction starts.”
In 2011, another Stanford research team addressed this challenge by coating silicon electrodes with ultrathin layers of titanium dioxide and iridium. That experimental water splitter produced hydrogen and oxygen for eight hours without corroding.
“Those were inspiring results, but for practical water splitting, longer-term stability is needed,” Dai said. “Also, the precious metal iridium is costly. A non-precious metal catalyst would be desirable.”
To find a low-cost alternative, Dai suggested that Kenney and his colleagues try coating silicon electrodes with ordinary nickel. “Nickel is corrosion-resistant,” Kenney said. “It’s also an active oxygen-producing catalyst, and it’s earth-abundant. That makes it very attractive for this type of application.”
Go deeper with Bing News on:
Low-cost water splitter
- Comment: Reshaping the supply chainon June 25, 2020 at 11:00 pm
Restructure, re-tool and apply our learnt lessons to supply chain setup, says Nigel Thomas, head of Aerospace & Defence - Private, Capgemini UK.
- Modular Drum Machine Creates Random Rhythmson June 20, 2020 at 5:00 pm
Don’t worry, the rhythms themselves aren’t random! That would hardly make for a useful drum machine. [kbob]’s creation does have the ability to randomly generate functional rhythms, though ...
- Self Built Interferometer Measures Nanometer Displacementon June 19, 2020 at 5:00 pm
[jrcgarry] used beam splitters from BluRay drives, mirrors from ebay and a 5mw laser diode. We’ve covered the use of interferometers before. But never an instrument built from scratch like this.
- The Best Gaming Headsets For 2020on June 16, 2020 at 6:55 pm
Cons: Expensive for a wired-only headset. PS4 Slim users need an HDMI splitter. Bottom Line: Astro Gaming's A40 TR headset with MixAmp Pro TR is a high-quality wired gaming headset/amp combination ...
- Beyond Covid-19: Building supply chain resilienceon June 10, 2020 at 11:03 pm
In the US, a team from MIT is working on an open-source, low-cost ventilator design while several start-ups are employing 3D printing to produce everything from nasal swabs to face shields and ...
Go deeper with Google Headlines on:
Low-cost water splitter
Go deeper with Bing News on:
- Love Island’s Luke M starts lockdown romance with Lucie Donlan after split with Demi Joneson June 29, 2020 at 10:42 am
LOVE Island’s Luke Mabbott has set his sights on fellow ITV2 star Lucie Donlan a month after splitting with Demi Jones, The Sun Online can exclusively reveal. Earlier this month, Demi, 21, ...
- Controversial housing development approved on chairman's vote after committee spliton June 29, 2020 at 7:11 am
A controversial housing development has been granted planning permission on a planning committee chairman's vote after councillors were divided. A reserved matters application for 94 homes to be built ...
- Why would Idaho’s congressional delegation split on the Great American Outdoors Act?on June 28, 2020 at 6:00 am
If Rep. Mike Simpson champions the bill, why would Sens. Mike Crapo and Jim Risch vote against it, writes Bob Kustra.
- An electrocatalyst for oxygen evolution reaction in water splittingon June 26, 2020 at 9:33 am
The transition from fossil fuels to renewable energy sources strongly depends on an availability of effective systems for energy conversion and storage. Considering hydrogen as a carrier molecule, ...
- Al2Pt for oxygen evolution reaction in water splittingon June 26, 2020 at 8:06 am
The transition from fossil fuels to renewable energy sources strongly depends on an availability of effective systems for energy conversion and storage. Considering hydrogen as a carrier molecule ...