May 042010
 

Inexpensive Metal Catalyst

The hydrogen economy that may one day replace the hydrocarbon economy came a step closer this week with the announcement that researchers have discovered an inexpensive new proton reduction catalyst – seventy times cheaper than the platinum commonly used now – that can significantly reduce the costs of producing hydrogen using electrolysis to split water into molecules of hydrogen and oxygen.

The important step was discovered by a team of researchers with the U.S. Department of Energy’s (DOE) Lawrence Berkeley National Laboratory (Berkeley Lab) and the University of California, Berkeley. “Our catalyst does not require organic additives, and can operate in neutral water, even if it is dirty, and can operate in sea water, the most abundant source of hydrogen on earth and a natural electrolyte,” said Hemamala Karunadasa, one of the co-discoverers of this complex. “These qualities make our catalyst ideal for renewable energy and sustainable chemistry.”

Karunadasa holds joint appointments with Berkeley Lab’s Chemical Sciences Division and UC Berkeley’s Chemistry Department. She is the lead author of a paper describing this work that appears in the April 29, 2010 issue of the journal Nature, titled “A molecular molybdenum-oxo catalyst for generating hydrogen from water.” Co-authors of this paper were Christopher Chang and Jeffrey Long, who also hold joint appointments with Berkeley Lab and UC Berkeley.

Hydrogen gas, whether combusted or used in fuel cells to generate electricity, emits only water vapor as an exhaust product, which is why this nation would already be rolling towards a hydrogen economy if only there were hydrogen wells to tap. However, hydrogen gas does not occur naturally and has to be produced.

Nature has developed extremely efficient water-splitting enzymes – called hydrogenases – for use by plants during photosynthesis, however, these enzymes are highly unstable and easily deactivated when removed from their native environment. Human activities demand a stable metal catalyst that can operate under non-biological settings.

Metal catalysts are commercially available, but they are low valence precious metals whose high costs make their widespread use prohibitive. For example, platinum, the best of them, costs some US$2,000 an ounce.

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